Atomically resolved orientational ordering of C60 molecules on epitaxial graphene on Cu(111).

نویسندگان

  • Minbok Jung
  • Dongbin Shin
  • So-Dam Sohn
  • Soon-Yong Kwon
  • Noejung Park
  • Hyung-Joon Shin
چکیده

A detailed understanding of interactions between molecules and graphene is one of the key issues for tailoring the properties of graphene-based molecular devices, because the electronic and structural properties of molecular layers on surfaces are determined by intermolecular and molecule-substrate interactions. Here, we present the atomically resolved experimental measurements of the self-assembled fullerene molecules on single-layer graphene on Cu(111). Fullerene molecules form a (4 × 4) superstructure on graphene/Cu(111), revealing only single molecular orientation. We can resolve the exact adsorption site and the configuration of fullerene by means of low-temperature scanning tunnelling microscopy (LT-STM) and density functional theory (DFT) calculations. The adsorption orientation can be explained in terms of the competition between intermolecular interactions and molecule-substrate interactions, where strong Coulomb interactions among the fullerenes determine the in-plane orientation of the fullerene. Our results provide important implications for developing carbon-based organic devices using a graphene template in the future.

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عنوان ژورنال:
  • Nanoscale

دوره 6 20  شماره 

صفحات  -

تاریخ انتشار 2014